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RuHCl(CO)(PPh3)3-Catalyzed Direct Amidation of Arene C-H Bond with Azides.

A new interesting article has been published in J Org Chem. 2018 Oct 23. doi: 10.1021/acs.joc.8b02123. [Epub ahead of print] and titled:

RuHCl(CO)(PPh3)3-Catalyzed Direct Amidation of Arene C-H Bond with Azides.

Authors of this article are:

Xiao X, Jia G, Liu F, Ou G, Xie Y.

A summary of the article is shown below:

We first report the direct ortho C-H amidation of arenes with azides by using a novel and inexpensive RuHCl(CO)(PPh3)3 catalyst. The reaction proceeds efficiently in high yield over a broad range of substrates without requirement of any additional silver salt or additive.

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