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Practical High Piezoelectricity in Barium Titanate Ceramics Utilizing Multiphase Convergence with Broad Structural Flexibility.

A new interesting article has been published in J Am Chem Soc. 2018 Oct 19. doi: 10.1021/jacs.8b07844. [Epub ahead of print] and titled:

Practical High Piezoelectricity in Barium Titanate Ceramics Utilizing Multiphase Convergence with Broad Structural Flexibility.

Authors of this article are:

Zhao C, Wu H, Li F, Cai Y, Zhang Y, Song D, Wu J, Lyu X, Yin J, Xiao D, Zhu J, Pennycook SJ.

A summary of the article is shown below:

Due to growing environmental concerns on the toxicity of lead-based piezoelectric materials, lead-free alternatives are urgently required, but so far have not been able to reach competitive performance. Here we employ a novel phase-boundary engineering strategy utilizing the multiphase convergence, which induces a broad structural flexibility in a wide phase-boundary zone with contiguous polymorphic phase transitions. We achieve an ultrahigh piezoelectric constant (d33) of 700 ± 30 pC/N in BaTiO3-based ceramics, maintaining > 600 pC/N over a wide composition range. Atomic-resolution polarization mapping by Z-contrast imaging reveals the coexistence of three ferroelectric phases (T+O+R) at the nanoscale with nanoscale polarization rotation between them. Theoretical simulations confirm greatly reduced energy barriers facilitating polarization rotation. Our lead-free material exceeds the performance of the majority of lead-based systems (including the benchmark PZT-5H) in the temperature range of 10 – 40 °C, making it suitable as a lead-free replacement in practical applications. This work offers a new paradigm for designing lead-free functional materials with superior electromechanical properties.

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