Synthesis and characterization of TiO2-V2O5-MCM-41 for catalyzing transesterification of dimethyl carbonate with phenol.
Authors of this article are:
Zhang J, Gao Y, Zhang J, Zhao J, Shen H.
A summary of the article is shown below:
A series of TiO2-V2O5-MCM-41 molecular sieve catalysts were prepared by the impregnation method. The prepared catalysts were characterized by different techniques including X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and N2 adsorption-desorption. These catalysts were applied in the catalytic synthesis of diphenyl carbonate (DPC) by the transesterification of dimethyl carbonate (DMC) with phenol. The synthesis results indicated that the catalysts possessed the high specific surface area and large pore volume and included titanium with four ligands. Due to the vanadium introduction into Ti-MCM-41, the catalytic activity was promoted, by-products were reduced, and the catalytic activity and stability of the catalyst were significantly improved. With 10%V-20%Ti-MCM-41 catalyst, the optimal synthesis results including the conversion rate of DMC of 33.88%, the selectivity of DPC of 35.84%, and the yield of DPC of 12.14% were obtained.
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This article is a good source of information and a good way to become familiar with topics such as:
Dimethyl carbonate;Diphenyl carbonate;Phenol;TiO2-V2O5-MCM-41;Transesterification
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