Iron-catalysed carbene-transfer reactions of diazo acetonitrile.
Authors of this article are:
Empel C Hock KJ Koenigs RM.
A summary of the article is shown below:
A continuous-flow protocol for the synthesis of diazo acetonitrile was developed. It was further applied in iron-catalysed insertion reactions of diazo acetonitrile into N-H and S-H bonds to yield valuable α-substituted acetonitrile, including gram-scale synthesis.
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